| 摘要 |
PROBLEM TO BE SOLVED: To obtain a carbon material having a highly controlled structure at a room temperature and a high temperature by subjecting a polyolefin derivative or an aromatic condensed cyclic hydrocarbon derivative containing a functional group elminable as an anion to electrode electrolytic reduction. SOLUTION: A polyolefin oligomer derivative of formula I (X1 to X4 are each F, Cl, Be, N<+> CR1 R2 R3 , etc.; X5 and X6 are each as shown for X1 to X4 but X5 and X6 are not F at the same time; R1 to R3 are each Cm H2m+1 (m<=4); n<=50) or an aromatic condensed cyclic hydrocarbon of formula II ((l) is 1, 2 or 3; C4l+2 is an aromatic condensed cyclic hydrocarbon group derived from benzene, naphthalene, etc.; X7 is as shown X1 to X4 ) is subjected to electrolytic reduction in a nonaqueous organic solvent having dissolved a supporting electrolyte in an inert gas atmosphere. In the operation, one of magnesium, zinc and aluminum or their alloys is used as an anode in two electrode method and one of magnesium, zinc and aluminum or their alloy is as an anode in a two electrode method and as an counter electrode in a three electrode method. |
