摘要 |
Waste phosphate sludge containing metals including iron and zinc are mixed with an alkali solution, and the mixture is dried and sintered at a temperature of about 500 DEG to 1300 DEG C. in the presence of a reductant, which may be either a reducing gas or a solid reductant. This results in conversion of the phosphate to a water-soluble salt, reduction of zinc to the metallic state and volatilization of the zinc from the reaction zone, and reduction of iron and other metallic elements to the metallic state. Leaching of the sinter cake with water recovers the soluble phosphate and frees the reduced metals for recovery in the form of fine-grained iron or iron alloy powder.
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