发明名称 |
Process for the preparation of D,L-menthol |
摘要 |
A continuous process is described for the preparation of D,L-menthol by catalytic hydrogenation of compounds which have the carbon skeleton of p-menthane containing at least one double bond and are 3-substituted by oxygen using hydrogen and/or by rearrangement of stereoisomers of menthol in the presence of hydrogen at temperatures of 150 DEG to 230 DEG C. and at pressures of 25 to 350 bar on fixed-bed catalysts made of support-free reduced shaped bodies made of pressed powders of cobalt (hydr)oxide, manganese (hydr)oxide, alkaline earth metal (hydr)oxides and, optionally, (hydr)oxides of elements of subgroup V and/or VI of the Periodic Table of the Elements.
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申请公布号 |
US5750803(A) |
申请公布日期 |
1998.05.12 |
申请号 |
US19960644783 |
申请日期 |
1996.05.10 |
申请人 |
BAYER AKTIENGESELLSCHAFT |
发明人 |
DARSOW, GERHARD;PETRUCK, GERD-MICHAEL |
分类号 |
B01J23/889;C07B61/00;C07C29/17;C07C29/20;C07C29/56;C07C35/12;(IPC1-7):C07C35/12;C07C27/00 |
主分类号 |
B01J23/889 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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