发明名称 PROCEDURE TO RECOVER COBALT CARBONYLS EMPLOYED AS CATALYSTS IN PREPARING N-ACYL-ALPHA-AMINO ACIDS BY AMIDOCARBONYLATION.
摘要 The present invention object is a procedure to recover cobalt carbonyl used catalyst. According to which firstly is prepared, by adding acid, a water-soluble cobalt salt which is later on precipitated as cobalt hydroxide. Then, this cobalt hydroxide is reacted with N-acyl-alpha-amino acid, for the preparation of which cobalt carbonyl catalyst is provided, and obtained cobalt fusion is transformed in cobalt carbonyl catalyst, in presence of a mixture formed by carbon monoxide and hydrogen.
申请公布号 MX9606201(A) 申请公布日期 1998.04.30
申请号 MX19960006201 申请日期 1996.12.06
申请人 HOECHST AKTIENGESELLSCHAFT 发明人 SANDRA BOGDANOVIC;HOLGER GEISSLER;KLAUS RAAB;MATTHIAS BELLER;HARTMUT FISCHER, W.
分类号 B01J31/20;B01J31/40;B01J38/68;C07C231/02;C07C233/47;(IPC1-7):C07C227/12 主分类号 B01J31/20
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