发明名称 A PROCESS FOR THE PREPARATION OF CYCLOPROPANE CARBOXYLIC ACIDS AND INTERMEDIATES THEREFOR.
摘要 <p>The compounds 3-(2,2-dichloro-3,3,3-trifluoro-1-hydroxypropyl)-2,2-dimethy l-(1R,3R)-cyclopropane carboxylic acid, cis-3-(2,2-dichloro-3,3,3-trifluoro-1-hydroxypropyl)-2,2-dim ethyl-cyclopropane carboxylic acid and (1R,5S)-4-(1,1-dichloro-2,2,2-trifluoroethyl)-6,6-dimethyl-3 -oxabicyclo[3.1.0]hexan-2-one occur as intermediates in a process for the preparation of insecticidally active cyclopropane carboxylate esters, said process starting from 6,6-dimethyl-4-hydroxy-3-oxabicyclo[3.1.0]hexan-2-one (Biocartol) which is reacted with the compound CF3-CC1X2 (X = halogen) in the presence of zinc.</p>
申请公布号 MX9800440(A) 申请公布日期 1998.04.30
申请号 MX19980000440 申请日期 1996.07.17
申请人 CHEMINOVA AGRO A/S. 发明人 PER DAUSELL KLEMMENSEN;HANS KOLIND-ANDERSEN;IB WINCKELMANN
分类号 C07D307/33;B01J23/06;C07B61/00;C07C51/09;C07C51/377;C07C61/35;C07C61/40;C07C62/02;C07D307/93;(IPC1-7):C07C61/35 主分类号 C07D307/33
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