| 摘要 |
A process is provided for the formation of aromatic polyesters directly from the reaction of dialkyl ester of an aromatic carboxylic acid with dihydric phenols. The polycondensation is carried out in the presence of (a) a condensing agent; (b) a catalyst selected from the group consisting of derivatives of Group I metals, derivatives of Group IV A metals, derivatives of Group IV B metals, and mixtures thereof; and (c) a co-catalyst selected from the group consisting of methanesulfonic acid, sulfuric acid, p-toluenesulfonic acid, alkanoic acid having the formula CnHxFyCOOH, where n is an integer from 1 to 4, x and y are integers from 0 to 2n+1, and the sum of x and y is 2n+1, and mixtures thereof; at suitable temperatures and pressure conditions and for sufficient period of time to form the aromatic polyester. |
