SOLID STATE POLYMERIZATION PROCESS FOR FOAMED POLY(ETHYLENE NAPHTHALATE)

摘要

This invention includes a process for preparing a solid state polymerized poly(ethylene naphthalate) (PEN) polymer or copolymer thereof comprising: (1) preparing a molten prepolymer with an intrinsic viscosity of from 0.25 dl/g to 0.50 dl/g, (2) dispsersing an inert gas into the molten prepolymer to form a foamed PEN prepolymer with a void fraction of from 0.10 to 0.50, (3) forming the foamed PEN prepolymer into granules, (4) devolatilizing the granular PEN prepolymer at a temperature of from 80 .degree.C to 140 .degree.C, (5) crystallizing the devolatilized PEN prepolymer at a temperature of from about 150 .degree.C to 260 .degree.C, and (6) solid state polymerizing the crystallized PEN prepolymer at a temperature of from 235 .degree.C to about 265 .degree.C to form a solid state polymerized PEN polymer or copolymer thereof.