METHOD OF PREPARING DI(1-ETHYL-1-ALKOXYALUMINIUM) [60] FULLERENES

摘要

chemical industry. SUBSTANCE: described is method of preparing di(1-ethyl-1- alkoxyaluminium 60) fullerenes of general formula I: wherein n is 1-6, R is Et, Bun and C60 is allotropic modification of carbon. Method comprises reacting fulleren 60 with excessive amount of 1-ethyl-1-alkoxy aluminium chloride of Et (RO) AlCl type and activated magnesium in the presence of titanocene chloride ((Cp2T;Cl2)) in argon atmosphere under normal conditions in solvents for 12-16 hours. Yield of final products is 48-72%. EFFECT: new organoaluminium compounds. 8 ex, 1 tbl