发明名称 |
Liquid phthalic anhydride recovery process using a rectification tower with benzoic acid control |
摘要 |
A process for recovering phthalic anhydride as a liquid from a vapor phase oxidation product which comprises mixing the vapor phase oxidation product having a temperature of about 130 DEG C. or greater with a first stream comprising maleic anhydride, benzoic acid present in an amount of less than 8 mole %, based on the total concentration of the first stream, and at least one compound selected from the group consisting of: citraconic anhydride and phthalic anhydride, in a rectification tower such that a substantial portion of the phthalic anhydride contained within the vapor phase oxidation product transfers from the vapor phase to a liquid phase and a substantial portion of the by-products contained in the first stream which are more volatile than phthalic anhydride transfer from the liquid phase to the vapor phase and wherein a vapor-to-liquid weight ratio in the range between about 2 to 20 is exhibited within the rectification tower, thereby forming a liquid phase phthalic anhydride product having a phthalic anhydride concentration in the range between about 50-100 wt. %.
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申请公布号 |
US5730844(A) |
申请公布日期 |
1998.03.24 |
申请号 |
US19960758559 |
申请日期 |
1996.11.29 |
申请人 |
EXXON CHEMICAL PATENTS INC. |
发明人 |
BAIEL, JAMES J.;JONES, LARRY O. |
分类号 |
C07C51/43;(IPC1-7):C07D307/89 |
主分类号 |
C07C51/43 |
代理机构 |
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