发明名称 |
Verfahren zur Herstellung niederer mehrwertiger Alkohole und neuer Katalysator auf Grund von Ruthenium verwendbar für dieses Verfahren |
摘要 |
A hydrogenation catalyst having a ruthenium base on activated carbon, suitable in particular for hydrogenolysis under pressure of higher polyhydric alcohols, comprising ruthenium supported on granulated active carbon, the said catalyst having: a specific surface area of 600 to 1000 m<2>/g; a total pore volume of 0.5 to 1.2 cm<3>/g; an apparent specific weight (bulk density) of 0.45 to 0.55 g/cm<3>; an actual specific weight of 1.9 to 2.3 g/cm<3>; a total volume of micropores having a radius smaller than 75 A of 0.4 to 0.55 cm<3>/g; and an ash content of 2 to 5 weight %. The catalyst is used in a method for continuous production in a fixed bed reactor of lower polyhydric alcohols, by means of hydrogenolysis under pressure of higher polyhydric alcohols. |
申请公布号 |
DE69314506(T2) |
申请公布日期 |
1998.03.12 |
申请号 |
DE1993614506 |
申请日期 |
1993.01.28 |
申请人 |
SUED CHEMIE MT S.R.L., MAILAND/MILANO, IT |
发明人 |
GUBITOSA, GIUSEPPE, I-28100 NOVARA, IT;CASALE, BRUNO, I-28062 CAMERI (NOVARA), IT |
分类号 |
B01J21/18;B01J23/46;B01J35/10;C07C29/00 |
主分类号 |
B01J21/18 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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