摘要 |
<p>Polysuccinimide is prepared by reacting ammonia gas with liquid maleic anhydride. The reaction is initially carried out at a temperature which is above the melting point of the maleic anhydride, but below the boiling point of liquid maleic anhydride for a time period sufficient for the liquid maleic anhydride to react with the ammonia gas to form a reaction product thereof. The reaction product is subsequently polymerized to polysuccinimide. The present method avoids the prior art problems of water removal and minimizes the need for ammonia handling equipment. The polysuccinimide product can be readily hydrolyzed to polyaspartic acid or a salt thereof, if desired.</p> |