发明名称 PRODUCTION OF LOW POLYMERIC ALPHA-OLEFIN
摘要 PROBLEM TO BE SOLVED: To enable to continuously obtain the subject compound in high yield and selectivity without generating a polymer as a by-product by feeding each component of a chromium-based compound catalyst in a specific rate to a reaction zone at the beginning of a reaction to initiate the reaction of an α- olefin. SOLUTION: In continuously reacting (B) α-olefin to polymerize into a low polymer using (A) a chromium-based catalyst consisting of a chromium compound (A1 ), a nitrogen-containing compound (A2 ) which is an amine, an amide or an imide and an alkylaluminum compound (A3 ), each component of the component A and the component B are fed to a reaction zone so that each of molar ratios A2 /A1 and A3 /A1 is made higher than the molar ratio in a stationary state to initiate the low polymerization reaction of the component B. It is preferable to feed each component of the component A and the component B to the reaction zone while keeping A1 and A3 apart not to come into contact with each other, thus, the objective compound can be obtained in high purity.
申请公布号 JPH1045634(A) 申请公布日期 1998.02.17
申请号 JP19960208537 申请日期 1996.08.07
申请人 MITSUBISHI CHEM CORP 发明人 ARAKI YOSHITAKE;NAKAMURA HIROFUMI;NANBA YOSHIAKI;OKANO TAKESHI
分类号 B01J31/12;C07C2/26;C07C11/00;C07C11/107;C10G50/00 主分类号 B01J31/12
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