发明名称 CATALYST FOR ETHYLENE POLYMERIZATION AND POLYMERIZATION OF ETHYLENE
摘要 PROBLEM TO BE SOLVED: To obtain a catalyst for ethylene polymerization, capable of providing a polymer having sufficiently high polymerization activity and high molecular weight and excellent in powder properties by simultaneously supporting zirconocene, etc., and titanocene on an ion exchangeable layered compound. SOLUTION: This catalyst comprises a product obtained by bringing (A) a metallocene-based transition metal compound containing zirconium or hafnium into contact with (B) a metallocene-based transition metal compound, (C) an ion-exchangeable layered compound or a non layered structural inorganic silicic acid salt and (D) an organoaluminum compound. Furthermore,α-olefin polymer obtained by preliminarily polymerizingα-olefin in the presence of (E) a contact product of the components A to D is preferably included in an amount of 0.01-1,000g based on 1g component C.
申请公布号 JPH1045819(A) 申请公布日期 1998.02.17
申请号 JP19960203677 申请日期 1996.08.01
申请人 MITSUBISHI CHEM CORP 发明人 KUROKAWA HIDEKI;IMAEDA KAORI;UEHARA YUMITO
分类号 C08F4/642;C08F4/60;C08F4/6592;C08F10/02;(IPC1-7):C08F4/642 主分类号 C08F4/642
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