发明名称 DIHALOGENATED FERROCENES AND PROCESSES FOR THE PREPARATION THEREOF
摘要 <p>The invention relates to a compound of formula I R1 is C1-C8alkyl, phenyl or phenyl substituted by from 1 to 3 C1-C4alkyl or C1-C4alkoxy substituents; R2 and R3 are each independently of the other hydrogen or C1-C12alkyl; and Hal is F, Cl, Br or I. Compounds of formula I are valuable intermediates for compounds of formula III which are also a subject of this invention: R1, R2, R3 and Hal are as defined above; R10 and R11 are identical or different and are C1-C12alkyl, C5-C12cycloalkyl, phenyl, C5-C12cycloalkyl substituted by C1-C4alkyl or by C1-C4alkoxy, or phenyl substituted by from one to three C1-C4alkyl, C1-C4alkoxy, -SiR4R5R6, halogen, -SO3M, -CO2M, -PO3M, -NR7R8, -[+NR7R8R9]X- or C1-C5fluoroalkyl substituents; or the group -PR10R11 is a radical of formula IV, IVa, IVb or IVc R4, R5 and R6 are each independently of the others C1-C12alkyl or phenyl; R7 and R8 are H, C1-C12alkyl or phenyl or R7 and R8 together are tetramethylene, pentamethylene or 3-oxa-1,5-pentylene; R9 is H or C1-C4alkyl; M is H or an alkali metal; X- is the anion of a monobasic acid.</p>
申请公布号 EP0820460(A1) 申请公布日期 1998.01.28
申请号 EP19960911992 申请日期 1996.04.02
申请人 NOVARTIS AG 发明人 PUGIN, BENOIT
分类号 B01J31/22;B01J31/16;B01J31/18;B01J31/24;C07B31/00;C07B35/02;C07B53/00;C07F17/02;(IPC1-7):C07F17/02 主分类号 B01J31/22
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