发明名称 ABSORPTIVE SEPARATION OF OPTICALLY ACTIVE DIOL DERIVATIVE
摘要 PROBLEM TO BE SOLVED: To economically, advantageously and simply separate the subject compound useful as a ferroelectric liquid crystal material or a medicinal intermediate forβ-blocking medicines or antibiotics, etc., in high optical purity from a mixture by an absorptive separation method by bringing a specific optically active diol derivative mixture into contact with an absorbent. SOLUTION: (A) An optically active diol derivative mixture obtained by reacting an optically active substance having a carbonyl such as (+) camphor or (-)-menthone with a mixture of R-isomer and S-isomer of a diol substance having an optically active point (e.g. 3-chloro-1,2-propanediol) is brought into contact with (B) an absorbent such as a zeolite [e.g. faujasite type zeolite (specifically Ba ion-exchange type X) or an aluminophosphate (specifically AlPO4 -5)].
申请公布号 JPH1017507(A) 申请公布日期 1998.01.20
申请号 JP19960170891 申请日期 1996.07.01
申请人 TORAY IND INC 发明人 KITAGAWA TETSUJI
分类号 B01J20/18;C07B57/00;C07C29/76;C07C31/20;C07C35/48;(IPC1-7):C07C35/48 主分类号 B01J20/18
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