Copolymers based on oxyalkyleneglycol alkenyl ethers and derivatives of unsaturated dicarboxylic acids

摘要

Copolymers based on oxyalkylene glycol-alkenyl ethers and derivs. of unsatd. dicarboxylic acids, comprise (a) 10-90 mols % of units of formula Ia and/or Ib (b) 1-89% of units of formula II and (c) 0.1-10% of units of formula IIIa or IIIb M = H, a mono- or di-valent metal cation, NH4 or an organic amine residue; a = 1, or if M is a divalent metal, a = 1/2; X = -OMa, -O-(CmH2mO)n-R1, -NHR2 and/or -NR2/2; R1 = H, a 1-20C aliphatic hydrocarbon gp., a 5-8C cycloaliphatic gp., or a (substd.) 6-14C aryl gp.; m = 2-4; n = 0-100; R2 = R1 or -CO-NH2; Y = O or NR2; R3 = H or a 1-5C aliphatic hydrocarbon gp.; p = 0-3; S = -H, -COOMa or -COOR5; T = -U1-(CH/CH3-CH2O)x-(CH2CH2O)y-R6, -W-R7, -CO-(NH-(CH2)3)s -W-R7, -CO-O-(CH2)z-W-R7, -(CH2)z-V-(CH2)z-CH=CH-R1, or -COOR5 if S = -COOR5 or COOMa; U1 = -CO-NH-, -O- or -CH2O-; U2 = -NH-CO-, -O- or -OCH2; V = -O-CO-C6H4-CO-O- or -W-; W = formula R4 = H or Me; R5 = 3-20C aliphatic hydrocarbon gp., 5-8C cycloaliphatic hydrocarbon gp. or 6-14 aryl gp.; R6 = formula R7 = formula r = 2-100; s = 1 or 2; z = 0-4; x = 1-150; y = 0-15.