发明名称 OXIDIZING CATALYST SYSTEM AND OXIDIZING METHOD USING THE SAME
摘要 PROBLEM TO BE SOLVED: To obtain an oxide corresponding to a substrate at a high conversion ratio and a high selectivity by oxidizing the substrate with molecular oxygen under mild conditions. SOLUTION: Under the existence of an oxidizing catalyst consisting of an imide compound (N-hydroxyphthalimide and the like) represented by a formula (wherein R<1> and R<2> represent substituents such as hydrogen atom, halogen atom and the like, and R<1> and R<2> may be bonded with each other to form a double bond or an aromatic or nonaromatic 5-12 membered ring. X represents O or HO and n=1 to 3) and an auxiliary catalyst (excluding phosphovanado molybdic acid) containing elements selected from the group of 2A group in the periodic table, transition metals (3A group - 7A group, 8 group and 2B group in the periodic table) and 3B group in the periodic table, a substrate (cycloalkanes, polycyclic hydrocarbons and aromatic compounds having methyl group or methylene group adjacent aromatic ring) is oxidized to obtain oxides (ketones, alcohols, carboxylic acid and the like).
申请公布号 JPH09327626(A) 申请公布日期 1997.12.22
申请号 JP19970023631 申请日期 1997.02.06
申请人 DAICEL CHEM IND LTD 发明人 ISHII YASUTAKA;NAKANO TATSUYA
分类号 C07D207/404;B01J31/02;B01J31/26;B01J31/28;B01J31/32;C07B33/00;C07B61/00;C07C27/12;C07C29/50;C07C33/035;C07C35/08;C07C35/44;C07C45/33;C07C47/52;C07C49/587;C07C49/76;C07C51/21;C07C53/126;C07C55/02;C07C55/12;C07C55/14;C07C55/18;C07C55/20;C07C59/347;C07C63/04;C07C63/06;C07C63/15;C07C63/16;C07C63/26;C07C67/313;C07C69/157;C07C69/734;C07C253/30;C07C255/13;C07D209/48 主分类号 C07D207/404
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