发明名称 Control of Molecular weight and end group functionality in polymers using unsaturated peroxy compounds as chain transfer agents
摘要 A process for the production of lower molecular weight polymers by free radical polymerization, characterized in that there is added to the polymerization system a compound of the general formula I n alkyl group, or a group capable of activating the vinylic carbon towards free radical addition; R2 is hydrogen or an optionally substituted alkyl, alkenyl, aryl, cycloalkenyl or cycloalkyl group or the group -COZ, where Z is R3 or OR3, where R3 is hydrogen or an optionally substituted alkyl, alkenyl or aryl group. X is a hydrogen atom, an alkyl or aryl group, or a halogen, and the two X groups may be the same or different. The invention also includes polymers or oligomers made by the process and novel compounds of the general formula I as defined above.
申请公布号 US5698648(A) 申请公布日期 1997.12.16
申请号 US19940202473 申请日期 1994.02.28
申请人 THE COMMONWEALTH OF AUSTRALIA COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATION 发明人 RIZZARDO, EZIO;MEIJS, GORDON FRANCIS;THANG, SAN HOA
分类号 C07C409/04;C07C409/16;C07C409/18;C07C409/38;C07C409/40;C08F2/38;C08F4/34;(IPC1-7):C08F4/34;C08F124/00 主分类号 C07C409/04
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