发明名称 CATALYTIC HYDROGENOLYSIS OF ORGANIC THIOCYANATES AND DISULFIDES TO THIOLS
摘要 A process for the preparation of a thiol comprising reacting hydrogen with a thiocyanate or disulfide wherein the reaction with thiocyanate is conducted in the presence of a catalyst comprising a Group VIII metal or a mixture thereof; and the reaction with thiocyanate or with disulfide is conducted in the presence of a catalyst comprising a Group VIII metal or mixture thereof in the presence of a modifier metal selected from a group consisting of Group IB, Group IIB, Group IIIA, Group IVA, Group VA and Group VIA metal or mixture thereof, said catalyst being on a porous insoluble support.
申请公布号 CA2250944(A1) 申请公布日期 1997.10.16
申请号 CA19972250944 申请日期 1997.04.04
申请人 E.I. DU PONT DE NEMOURS AND COMPANY 发明人 JACOBSON, STEPHEN ERNEST
分类号 C07C319/02;C07C319/06;C07C321/02;C07C323/00;C07C323/03;(IPC1-7):C07C319/06 主分类号 C07C319/02
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