发明名称 Methods of sputtering a metal onto a substrate and semiconductor processing apparatus
摘要 An aluminum sputtering process, particularly useful for filling vias and contacts of high aspect ratios formed through a dielectric layer and also useful for forming interconnects that are highly resistant to electromigration. A liner or barrier layer (150) is first deposited by a high-density plasma (HDP) physical vapor deposition (PVD, also called sputtering) process, such as is done with an inductively coupled plasma. If a contact (140) is connected at its bottom to a silicon element (144), the first sublayer (160) of the liner layer is a Ti layer, which is silicided to the silicon substrate. The second sublayer (162) comprises TiN, which not only acts as a barrier against the migration of undesirable components into the underlying silicon but also when deposited with an HDP process and biased wafer forms a dense, smooth crystal structure. The third sublayer (164) comprises Ti and preferably is graded from TiN to Ti. Over the liner layer, an aluminum layer (156) is deposited in a standard, non-HDP process. The liner layer allows the hottest part of the aluminum deposition to be performed at a relatively low temperature between 320 and 500 DEG C, preferably between 350 and 420 DEG C, while still filling narrow plug holes, and the TiN does not need to be annealed to form an effective barrier against diffusion into the silicon. A horizontal interconnect formed by the inventive process is resistant to electromigration. <IMAGE>
申请公布号 EP0799903(A2) 申请公布日期 1997.10.08
申请号 EP19960305733 申请日期 1996.08.02
申请人 APPLIED MATERIALS, INC. 发明人 XU, ZHENG;FORSTER, JOHN;YAO, TSE-YONG;NULMAN, JAIM;CHEN, FUSEN
分类号 C23C14/04;C23C14/06;C23C14/14;C23C14/34;C23C14/35;C23C14/56;H01L21/285;H01L21/768;H01L23/485;H01L23/522;H01L23/532 主分类号 C23C14/04
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