发明名称 PRODUCTION OF AROMATIC POLYCARBONATE RESIN, AND AROMATIC POLYCARBONATE RESIN
摘要 PROBLEM TO BE SOLVED: To obtain a high-quality arom. polycarbonate resin excellent in color tone and heat stability by using a rare earth element compd. as a catalyst for transesterification of an arom. dihydroxy compd. with a carbonate precursor. SOLUTION: A rare earth element compd. of the formula (wherein Ln is scandium, yttrium, lanthanum, and a lanthanoid element; X is a monovalent or bivalent element, atomic group or substituent; R<1> to R<3> are each a 1-20C alkyl group or an aryl group; and 0<q+r+s<=3; provided that kp+q+r+s=3 wherein k is the valence of X) is used in an amt. of 1×10<-4> to 1×10<-8> mol in terms of rare earth element per mol of an arom. hydroxy compd. as a catalyst for transesterification of the arom. hydroxy compd. with a carbonate precursor to prepare an arom. polycarbonate resin.
申请公布号 JPH09241371(A) 申请公布日期 1997.09.16
申请号 JP19960054848 申请日期 1996.03.12
申请人 MITSUBISHI CHEM CORP 发明人 KASHIWAGI TAKESHI;SHOJI HIDEKAZU;KIMURA MASATOSHI;NUKII MASAHIRO
分类号 C08G64/04;C08G64/00;C08G64/20;C08G64/30;(IPC1-7):C08G64/30 主分类号 C08G64/04
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