| 摘要 |
Batteries based on lead chemistry, e.g., lead-acid batteries, are substantially improved through the use of a particular positive material. This material is formed by the electrochemical conversion of tetrabasic lead sulfate (TTB) where this TTB is synthesized at a pH in the range 9.3 to 12 and under reaction conditions that provide a substantial excess of sulfate to the reactive lead. The resulting materials provide needle-like structures with a width generally in the range 3 to 1 mu m. The relative narrow needles, when employed on the positive electrode of a lead acid battery, improve the efficiency of formation, provide good adhesive to the positive plate, extend battery life, as well as, yield excellent capacity per gram of active material.
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