发明名称 PRODUCTION OF AROMATIC HYDROXY COMPOUND
摘要 PROBLEM TO BE SOLVED: To produce an aromatic hydroxy compound which is useful as a raw material or an intermediate for a variety of organic chemicals, for example, microbicidal agents, chelating agents and photography developing agents in high selectivity in no use of an expensive raw material. SOLUTION: An aromatic hydroxy compound (for example, phenol, cresol or catechol) is produced by photooxidation of an aromatic compound (for example, benzene) in the presence of a catalyst comprising porous metallosilicate and titanium dioxide, preferably by photooxidizing <=2mol/L of an aromatic compound, for example, benzene, using oxygen. The amount of the catalyst used in the reaction is preferably 0.2-100mg per 1cc of the solvent. In the photoirradiation, a mercury lamp, a xenon discharge tube or other ultraviolet light sources can be utilized, and the light of wavelength of <=320nm is preferably cut off by using a UV filter.
申请公布号 JPH09208511(A) 申请公布日期 1997.08.12
申请号 JP19960013260 申请日期 1996.01.29
申请人 SUMITOMO METAL IND LTD 发明人 MASAKI YASUHIRO;YAO TADASHI
分类号 B01J21/06;B01J35/02;C07B61/00;C07C37/58;C07C39/04;C07C39/06;C07C39/08 主分类号 B01J21/06
代理机构 代理人
主权项
地址