发明名称 Process for the preparation of a bridged metallocene compound as well as a catalyst component and a process for the polymerization of olefins
摘要 The invention relates to a process for the preparation of a bridged metallocene compound in which: (I) a bridged double ligand, reacting with a proton acceptor, is converted into a bridged double anion (II) the double anion is converted into the bridged metallocene compound through reaction with a compound of a group 4b, 5b or 6b metal from the Periodic System of Elements. reaction (II) being carried out in a liquid dispersant which a) comprises one or more weak Lewis bases, the conjugated acid of which has a dissociation constant pKa for which the following holds:pKa</=-2.5,b) contains at most 1 mole equivalent, relevant to the metal compound, of strong Lewis base, the conjugated acid of which has a pKa that is higher than -2.5. The invention further relates to a catalyst component for the polymerization of olefins and a process for the polymerization of olefins and a polyolefin.
申请公布号 US5646083(A) 申请公布日期 1997.07.08
申请号 US19940202738 申请日期 1994.02.28
申请人 DSM N.V. 发明人 VAN BEEK, JOHANNUS A.M.
分类号 C07F17/00;C07F17/02;C08F4/60;C08F4/62;C08F4/64;C08F4/642;C08F4/659;C08F4/6592;C08F10/00;(IPC1-7):C08F4/42 主分类号 C07F17/00
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