摘要 |
Process for preparing pentafluoroethane (125) containing amounts of 115 lower than 0.02% by weight wherein pentafluoroethane is obtained by a dismutation process of tetrafluorochloroethane CF3CHClF (HCFC-124) in gaseous phase in the presence of a chrome oxide catalyst (CR2O3) supported on a AlF3 support, wherein one operates at temperatures from 140-180 DEG C for contact times comprised between 15-30 seconds, from >180 DEG C to 240 DEG C for contact times between 5 to 15 seconds, from >240 DEG C to 260 DEG C for contact times between 1 to 5 seconds, from >260 DEG to 300 DEG C for contact times between 0.1 to 1 second. |