发明名称 |
Verfahren zur Herstellung von Enolethern |
摘要 |
The preparation of enol-ethers of formula R3R4C=C(OR1)R2 is by gas phase reaction at 100-550 (especially 200-350) degrees C and 0.001-5 bar of acetals or ketals of formula R3R4HC-C(OR1)(OR1')R2 on a heterogeneous highly porous catalyst which is an oxide of a Gp. II, III or IV or sub-Gp. II or IV element, the catalyst having a pH of 7-14, a porosity of 40-80% and a BET surface area of 0.5-250 m<2>/g. R1-5 = 1-20 C alkyl, 2-20 C alkenyl or 7-20 C phenylalkyl; R2-4 = H, aryl, CN, COOR5, 1-12 C alkyl (optionally 1-3 times substituted or interrupted by COOR5, CO, CN or 1-12 C alkoxy), aryl or 7-12 C phenylalkyl (each optionally 1-3 times substituted by 1-12 C alkyl, 1-12 C alkoxy, halogen or CN); R2/R4 or R3/R4 = together 3-10 C alkylene or 2-20 C alkylidene; and R1' = R1, but not necessarily the same. |
申请公布号 |
DE19544450(A1) |
申请公布日期 |
1997.06.05 |
申请号 |
DE1995144450 |
申请日期 |
1995.11.29 |
申请人 |
BASF AG, 67063 LUDWIGSHAFEN, DE |
发明人 |
SCHROEDER, JUERGEN, DR., 67071 LUDWIGSHAFEN, DE;BOECK, STEFAN, DR., 67069 LUDWIGSHAFEN, DE;EBEL, KLAUS, DR., 68623 LAMPERTHEIM, DE |
分类号 |
B01J21/04;B01J21/06;B01J21/08;C07B61/00;C07C41/28;C07C43/16;C07C43/166;C07C43/176;C07C67/327;C07C69/734;(IPC1-7):C07C43/16;C07C67/317;C07C255/15;C07C69/708 |
主分类号 |
B01J21/04 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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