发明名称 NEW ALKENYLSUCCINIC HALF ESTER COMPOUND AND ITS COPOLYMER AND PAPER MANUFACTURING ADDITIVE USING THE SAME AS ACTIVE INGREDIENT
摘要 PROBLEM TO BE SOLVED: To obtain an allyl compound suitable as a raw material for plasticizers and synthetic resins having amphipathic effect, namely, both solubility to water and dispersibility, such as heat-resistant resins, and useful for a paper manufacturing additive having a combination of paper strengthening ability and sizing performance. SOLUTION: This compound, an alkenylsuccinic half ester compound of formula I (R1 and R2 are each H, a 1-23C alkyl, etc.; R1 +R2 is of 3-46C; R3 is H or methyl; M is H, an alkali metal, etc.) or formula II, is obtained by reaction of an alkenylsuccinic anhydride (e.g. derived from a 6-49Cα-olefin such as 1-hexene) with an equivalent of an alcohol or methallyl alcohol in a solventless or organic solvent system under normal or higher pressures pref. at 10-100 deg.C for 30min to 20h. Besides, 10.0-90.0wt.% of the compound(s) of formula I and/or formula II is copolymerized with 10.0-99.9wt.% of a vinyl compound to obtain a polymeric compound bearing this compound on the side chain.
申请公布号 JPH0952867(A) 申请公布日期 1997.02.25
申请号 JP19950203093 申请日期 1995.08.09
申请人 MITSUI TOATSU CHEM INC 发明人 TANABE MASARU;TAKAGI TOSHIHIKO;ITO HIROSHI;YANAGI MASAYUKI;WATABE YASUYOSHI
分类号 C07C69/593;C07C69/602;C08F20/10;C08F222/26;D21H17/34;D21H17/37;D21H21/16;(IPC1-7):C07C69/593 主分类号 C07C69/593
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