发明名称 PRODUCTION OF ALKOXYNAPHTHALENECARBOXYLIC ACID DERIVATIVE
摘要 PROBLEM TO BE SOLVED: To obtain a compound useful as an intermediate for producing medicines, agrochemicals and functional materials by a simple method and in high purity. SOLUTION: This alkoxynaphthalenecarboxylic acid derivative is expressed by formula I (X1 to X4 are each H, an alkyl, an aryl, etc.; R1 is H, an aryl, an aralkyl, etc.), e.g. 2-n-hexyloxynaphtalene-6-carboxylic acid. The compound of formula I is obtained by reacting a hydroxynaphthalenecarboxylic acid (e.g. 1-hydroxynaphthalene-2-carboxylic acid) or a hydroxynaphthalenecarboxylic acid ester derivative (e.g. 1-hydroxynaphthalene-5-carboxyloc acid) with an alkylating agent (e.g. methyl bromide) to obtain a basic salt of the derivative of formula I, which is separated as a crystal form or an aqueous solution, and further being in contact it with an acid (e.g. hydrochloric acid).
申请公布号 JPH0952863(A) 申请公布日期 1997.02.25
申请号 JP19950202289 申请日期 1995.08.08
申请人 MITSUI TOATSU CHEM INC 发明人 OTSUJI ATSUO;ISHIDA TSUTOMU;TOTANI YOSHIYUKI;HIRAO GENICHI;KAYASHIMA HIROE;NAKATSUKA MASAKATSU
分类号 C07B53/00;C07C51/367;C07C65/24;C07C67/31;C07C69/94;(IPC1-7):C07C65/24 主分类号 C07B53/00
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