发明名称 |
Process for the preparation of 3-aminomethyl-3,5,5-trimethyl cyclohexylamine |
摘要 |
Prepn. of 3-aminomethyl-3,5,5-tri- methylcyclohexylamine (I) comprises reacting 3-cyano-3,5,5-tri- methylcyclohexanone (II) with (I) and subsequently or simultaneously adding ammonia under a H2 pressure of 50-300 bar in the presence of a hydrogenation catalyst at a temp. of 20-150 degrees C, and carrying out the reaction without removing the water of reaction formed. Pref. the mol. ratio (II):(I)=0.5:1 to 5:1 and the wt. ratio ammonia:(II)=0.1:1 to 10:1. The hydrogenation catalyst pref. contains at least one element chosen from Cu or an element of gp. VIII, esp. Raney-Co, Raney-Ni, Co or Co-carrier catalysts. The reaction is pref. carried out essentially in the absence of a solvent.
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申请公布号 |
EP0757980(A1) |
申请公布日期 |
1997.02.12 |
申请号 |
EP19950112482 |
申请日期 |
1995.08.09 |
申请人 |
BASF AKTIENGESELLSCHAFT |
发明人 |
WITZEL, TOM, DR.;VOIT, GUIDO, DR. |
分类号 |
C07B61/00;C07C209/26;C07C209/48;C07C209/52;C07C211/36;C07C253/30;(IPC1-7):C07C209/48 |
主分类号 |
C07B61/00 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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