Rubber devulcanization process

摘要

A process for devulcanizing a rubber vulcanizate by desulfurization involves suspending a rubber vulcanizate crumb in a solvent which preferably swells the rubber vulcanizate before or during the devulcanization reaction and adding an alkali metal, such as sodium, to the suspension. The alkali metal cleaves mono-, di- and polysulfidic cross-linkages in the rubber vulcanizate to liberate rubber polymer having a molecular weight substantially equal to that of the rubber polymer prior to vulcanization. Carbon black may also be recovered for re-use in accordance with the process of the present invention. Devulcanized rubber may be subjected to a re-vulcanization reaction without separation of rubber polymer from the solvent by addition of an appropriate curing mixture.