发明名称 |
Process and catalyst for the preparation of aromatic amines by hydrogenation in the gas phase |
摘要 |
Prodn. of aromatic amines of formula (I) comprises gas phase hydrogenation of nitroaromatics of formula (II) with H2 over a stationary catalyst of Pd on a graphite of graphitised coke support with a BET surface area of 0.2-10 m<2>/g. The novel features are that (a) the catalyst contains more than 1.5 to 7 wt.% Pd w.r.t. total catalyst and (b) the H2 supply to the catalyst is 30-6000 equiv./NO2 gp. equiv.: R1, R2 = H, Me, Et or NH2; R3, R4 = H. Me, Et or NO2. Also claimed is the catalyst per se. |
申请公布号 |
EP0748789(A2) |
申请公布日期 |
1996.12.18 |
申请号 |
EP19960108855 |
申请日期 |
1996.06.03 |
申请人 |
BAYER AG |
发明人 |
LANGER, REINHARD, DR.;BUYSCH, HANS-JOSEF, DR.;PENTLING, URSULA, DR. |
分类号 |
B01J21/18;B01J23/44;C07B61/00;C07C209/36;C07C211/45;C07C211/50 |
主分类号 |
B01J21/18 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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