发明名称 |
PROCESS TO MAKE ALLYL CHLORIDE AND REACTOR USEFUL IN THAT PROCESS |
摘要 |
<p>Allyl halide is produced in high yields and purity with minimal carbon formation using a process of: (1) initially reacting propylene and molecular halogen in a molar ratio of at least 2.5:1 in a "continuously stirred tank reactor" (CSTR) zone under conditions suitable to provide a reaction temperature of 400 DEG C to 525 DEG C to partially convert propylene and chlorine into allyl chloride; and (2) feeding an effluent from Step (1) into a plug-flow reactor zone where the reaction is continued at a temperature of 400 DEG C to 525 DEG C until essentially all of the chlorine is consumed. A preferred reactor for the process contains: (1) a spherical, egg-shaped or oval reactor zone; (2) a tubular reactor zone attached to the spherical, egg-shaped or oval reactor zone; (3) one or more inlets for injecting gaseous reagents into the spherical, oval or egg-shaped reactor zone; and (4) one or more outlets from the tubular reactor zone for withdrawing a gaseous product.</p> |
申请公布号 |
WO9637450(A1) |
申请公布日期 |
1996.11.28 |
申请号 |
WO1996US02793 |
申请日期 |
1996.02.27 |
申请人 |
THE DOW CHEMICAL COMPANY |
发明人 |
TIRTOWIDJOJO, MAX, M.;BECKETT, PAUL, C.;BAKER, JOHN, F. |
分类号 |
C07C17/06;B01J19/00;B01J19/18;B01J19/24;C07C17/10;C07C21/067;(IPC1-7):C07C17/10 |
主分类号 |
C07C17/06 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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