发明名称 PREPARATION OF LARGELY ISOMERICALLY PURE .ALPHA.-BISOXIMES
摘要 Described is a method of preparing essentially pure .alpha.-bis-oxime isomers of the formula (Ia): R1O-N=CR2-CR3=N-OR4, in which the groups R1O- and R2 are in the cis configuration with respect to the N=C bond, from a mixture of the cis and trans isomers (Ia and Ib), the various groups being defined as follows: R1, R4 are hydrogen, or an organic carbon group; R2 is hydrogen, cyano, nitro, hydroxy, amino, halogen or an organic group which may be bound directly or via an oxygen, sulphur or nitrogen atom to the main chain; R3 is hydrogen, cyano, nitro, hydroxy, amino, halogen, alkyl, haloalkyl, alkoxy, haloa lkoxy, alkylthio, alkylamino, dialkylamino or cycloalkyl, Said method is characterized in that the mixture is treated in an organic solven t with a Lewis acid.
申请公布号 CA2216000(A1) 申请公布日期 1996.10.17
申请号 CA19962216000 申请日期 1996.03.25
申请人 BASF AKTIENGESELLSCHAFT 发明人 SAUTER, HUBERT;BENOIT, REMY;BAYER, HERBERT;MUELLER, RUTH;GOETZ, NORBERT
分类号 C07D231/12;C07B61/00;C07C249/04;C07C249/12;C07C249/14;C07C251/38;C07C251/48;C07C255/62;C07D261/08;(IPC1-7):C07C251/34;C07C255/64;C07C319/20;C07C323/47 主分类号 C07D231/12
代理机构 代理人
主权项
地址