CATALYST AND PROCESS FOR PREPARING AMIDES

摘要

A platinum complex useful as a catalyst for converting nitriles into amides comprises a platinum complex of dialkyl phosphine of stoichiometric formula: PtX(R2POHOPR2)(PR2OH) where R is an alkyl, alicyclic, chiral, alkylaryl group or substituted alkyl, alicyclic, chiral, alkaryl group or the two R groups attached to one phosphorus atom can form a heterocyclic ring with the phosphorus atom and X is H or a halide. The conversion takes place under reflux conditions to give a high yield of the amide.