摘要 |
High capacity solid state cyanocobaltate complexes represented by the chemical formula: <CHEM> where: A is alkali metal atom, alkaline earth metal atom, Zn, Cd or Hg atom; a is any number from 0 to 2.5 each R is independently C1-C10 substituted or unsubstituted alkyl, aryl or aralkyl; or a long chain hydrocarbon polymer b is any number from greater than zero to 3 z is 1, 2 or 3; n is any number from 3 to 5; x is n-2; p is any number from greater than zero to 6; and S is a ligand which is capable of coordinating with [(A)a(R4N)b]<z+>, Co or both. are capable of chemically binding oxygen to form novel oxygen adducts, thereby selectively removing oxygen from an oxygen-containing fluid stream. The bound oxygen may be recovered from the complexes by increasing the temperature or by reducing the partial pressure of O2 above the adduct. |
申请人 |
AIR PRODUCTS AND CHEMICALS, INC., ALLENTOWN, PA., US |
发明人 |
RAMPRASAD, DORAI, ALLENTOWN, PA 18104, US;PEZ, GUIDO PETER, ALLENTOWN, PA 18103, US;PEARLSTEIN, RONALD MARTIN, MACUNGIE, PA 18062, US;MEIER, INGRID KRISTINE, ASBURY, NJ 08802, US |