PILLARED HYDROTALCITE INTERCALATED ANION PHOSPHINE METAL COMPLEX AND METHOD OF PRODUCING THE SAME

摘要

TtLl(SP)m-[M(II)1-xM(III)x(OH)2 X+(Ax/n)= yH2O) is one that anion phosphine metal complex(eqn 1: TtLl(SP)m) is coupled between layers of hydrotalcite compound (eqn 2: [M(II)1-xM(III)x(OH)2 X+(Ax/n)= yH2O), where T is Rh, Co, Ru, Ir, Pt, Ni, Cu, Mn, Fe, Pd, Ag or Au; L is Cl, CO, NO, COD, H, SR, OH, NH3 or alkylamine; SP is anion phosphine ligand, sulfonated or carbonated alkyl or anion allyl phosphine; t is 1-2; l is 0-8; m is 1-8; M(II) is Mg, Ni, Co, Fe, An, Cu or Li; M(III) is Al, Cr or Fe; A is organic or inorganic anion with quantity of electric charge of n; X is 0.2-0.4; n is the quantity of electric charge of A; y is the number of water molecule.