发明名称 |
Process for a rectificative separation of (meth)acrylic acid from a hydrophobic mixture containing crude (meth)acrylic acid |
摘要 |
A process for the sepn. of (meth)acrylic acid (I) from a mixt. contg. (a) (I), (b) inert, hydrophobic organic liq. with a higher b.pt. than (I) as main component and (c) lower aldehydes as minor components, comprises rectification with the addn. of a prim. amine and/or salts thereof (II). Also claimed are processes for the prodn. of (I) by gas-phase oxidn. of a 3C/4C starting material (III). Pref. liq. (b) contains diphenyl ether (DPE), and pref. comprises a mixt. of 70-75 wt.% DPE and 25-30 wt.% biphenyl contg. 0.1-25 wt.% (w.r.t. the mixt.) of dimethyl o-phthalate. Amine (II) is a hydrazine deriv., pref. the hydrazide of a carboxylic acid, esp. pref. adipic acid dihydrazide.
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申请公布号 |
EP0717029(A2) |
申请公布日期 |
1996.06.19 |
申请号 |
EP19950118901 |
申请日期 |
1995.12.01 |
申请人 |
BASF AKTIENGESELLSCHAFT |
发明人 |
HERBST, HOLGER, DR.;NESTLER, GERHARD, DR.;HAMMON, ULRICH, DR.;DARLINGTON, JERRY |
分类号 |
C07C57/055;C07C51/44;C07C51/46;C07C57/07;C07C57/075;(IPC1-7):C07C57/04 |
主分类号 |
C07C57/055 |
代理机构 |
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