| 摘要 |
The invention relates to compounds of the general formula (I) D.M.G.Y, wherein D stands for one or more moieties comprising dithiocarbamic functional groups of the formula R<1>R<2>NCS2, where R<1> and R<2> are alkyl or together form alkylene which may contain one or more heteroatoms; M is a metal atom having atomic number higher than 20 and atomic volume less than 20 cm<3>, selected from manganese, iron, cobalt, nickel, zinc, copper, molybdenum, rhodium, silver, tin, samarium, platinum, gold, mercury and lead; G stands for a moiety carrying guanidine, e.g. arginine, blasticidine, alkylguanidine, streptomycin, 2-benthiazolyl guanidine, preferably bis (8-guanidino)-octylamine, alkylguanidine, Y is a moiety of acidic function and is selected from an inorganic or organic acid or a derivative thereof, preferably mineral acids (preferably phosphoric acid, phosphonic acid and phosphinic acid and derivatives thereof, hydrochloric acid, sulfuric acid, boric acid, nitric acid; organic carboxylic acids, preferably formic acid, acetic acid, propionic acid, stearic acid, pyruvic acid, lactic acid, benzoic acid, o-methyl benzoic acid, oxalic acid, tartaric acid, citric acid, succinic acid, adipic acid, ethoxyacetic acid, glucuronic acids, salicylic acid, cinnamic acid, deoxycholic acid, 3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl) acrylic acid, allofuranoic acid and an organic derivative of phosphoric acid, phosphonic acid, phosphinic acid, preferably phosphatidyl derivative, an alkylhydrophosphonic acid, 0-[1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)-2-but-2-yl)]-P-(2-carboxyethyl)-P-methyl phosphinate and an organic sulfate, preferably dodecyl sulphate and sulphonic acid, benzylamino benzene sulphonic acid, lignine sulphonic acid, 4-dimethylamino benzene diazosulphonate; a dithiocarbamic acid derivative and a phenol derivative, 2'-(2,4-dichlorophenoxy)-4'-chlorophenol, 2-(1-methyl-heptyl)-4,6-dinitrophenol, 2,4,5-trichlorophenol, 2-sec-butyl-4,6-dinitrophenol, 2-(1,1-dimethylethyl)-4,6-dinitrophenol. |
