| 摘要 |
<p>Ion-conductive polymers with high ion conductivity and containing covalently bound ion complexes of one of formulas (Ia-Ic), wherein M?+ is H+, Li+, Na+, or K+¿; m is an integer in the range 0-4; m' is an integer in the range 0-7; m' is an integer in the range 0-8; and each R independently is halogen; -CO-O?-, -CO-O-,M+¿, or -SO¿2-O?-,M+; cyano; nitro; C¿1-5? alkoxy; optionally substituted phenyl or phenoxy; -CONR?5R6 or -NR5R6¿ where R?5 and R6¿ independently are hydrogen, C¿1-5? alkyl, optionally substituted phenyl, phenylcarbonyl, or C1-6 alkanoyl; -N(R?5)-CO-R7¿ where R7 is hydrogen, C¿1-5? alkyl, C2-5 alkenyl, C2-5 alkynyl, or optionally substituted phenyl; R?7-CO-, R7¿-O-CO-, R7-CO-O-, or R7-O-CO-O-; cycloheptatrienyl; or one of the groups R is a ion complex of the type Ia, Ib, or Ic with the proviso that R cannot be a further ion complex of the type Ia, Ib, or Ic; or two groups R bound to two adjacent carbon together form a divalent aliphatic or alicyclic group with 3-8 carbon atoms and having at least 2 C-C double bonds, -CO-O-CO-, -CO-S-CO-, or -CO-N(R7)-CO-; and the free bond 'a', either directly or through an intervening group, is bound to the polymer backbone.</p> |
