发明名称 |
HYDROGENATION CATALYST FOR CARBOXYLIC ACID AND METHOD FOR HYDROGENATION OF CARBOXYLIC ACID USING SAID CATALYST |
摘要 |
PURPOSE: To provide a method of forming tetrahydrofuran by hydrogenating dicarboxylic acids, particularly maleic anhydride, using a hydrogenation catalyst with a carrier having an improved precious metal component and a Re component of the group VIII metals as the catalytic components. CONSTITUTION: A hydrogenation catalyst for carboxylic acids is provided with a silica carrier having supported thereon a precious metal component and a Re component of the group VIII metals in the periodic table and consisting of a meso-porous body having a BET surface area of at least 120m<2> /g and an average pore size of 2.0-45.0nm in diameter or a sharp distribution of the pore with a diameter of 2<D(pore diameter)<50nm. A method of hydrogenating dicarboxylic acids comprises hydrogenating at least a member selected from the dicarboxylic acids having 4 carbon atoms and the acid anhydrides at a temperature of 130-350 deg.C and at a hydrogen pressure of 5.0-20.0MPa in the presence of the hydrogenation catalyst in order to form the corresponding cyclic ethers and/or lactones. |
申请公布号 |
JPH08141396(A) |
申请公布日期 |
1996.06.04 |
申请号 |
JP19940316039 |
申请日期 |
1994.11.28 |
申请人 |
MITSUBISHI CHEM CORP |
发明人 |
HARA YOSHINORI;KUSAKA HARUHIKO;INAGAKI HIROKO |
分类号 |
C07D307/08;B01J23/656;C07B61/00;C07D307/33 |
主分类号 |
C07D307/08 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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