Diode laser pumped Raman gas analysis system with reflective hollow tube gas cell

摘要

A method and apparatus for determining the composition and concentration of gases present in a gas sample by measurement of the spectrum of Raman scattered light from these gases. A diode laser illuminates the unknown gas which is contained inside a long hollow tube having a highly reflective interior wall. A laser line pass filter at an entrance aperture of the hollow tube prevents all wavelengths except specific wavelengths characteristic of the laser from entering the long hollow tube. The laser beam and Raman scattered light from the gas sample reflect inside the hollow tube from the highly reflective interior wall. A laser line rejection filter at an exit aperture of the hollow tube prevents the laser beam from exiting the hollow tube but transmits the Raman scattered light from the gas sample. A spectrograph detector or array of discrete filters and detectors detects the Raman scattered light. The output of the detector(s) is then analyzed to identify the constituents of the unknown gas sample and the concentrations of the constituents.