| 摘要 |
<p>The invention relates to compounds of the general formula (I) D.M.G.Y, wherein D stands for one or more moieties comprising dithiocarbamic functional groups of the formula R1R2NCS2, where R?1 and R2¿ are alkyl or together form alkylene which may contain one or more heteroatoms; M is a metal atom having atomic number higher than 20 and atomic volume less than 20 cm3, selected from manganese, iron, cobalt, nickel, zinc, copper, molybdenum, rhodium, silver, tin, samarium, platinum, gold, mercury and lead; G stands for a moiety carrying guanidine, e.g. arginine, blasticidine, alkylguanidine, streptomycin, 2-benthiazolyl guanidine, preferably bis (8-guanidino)-octylamine, alkylguanidine, Y is a moiety of acidic function and is selected from an inorganic or organic acid or a derivative thereof, preferably mineral acids (preferably phosphoric acid, phosphonic acid and phosphinic acid and derivatives thereof, hydrochloric acid, sulfuric acid, boric acid, nitric acid; organic carboxylic acids, preferably formic acid, acetic acid, propionic acid, stearic acid, pyruvic acid, lactic acid, benzoic acid, o-methyl benzoic acid, oxalic acid, tartaric acid, citric acid, succinic acid, adipic acid, ethoxyacetic acid, glucuronic acids, salicylic acid, cinnamic acid, deoxycholic acid, 3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl) acrylic acid, allofuranoic acid and an organic derivative of phosphoric acid, phosphonic acid, phosphinic acid, preferably phosphatidyl derivative, an alkylhydrophosphonic acid, 0-[1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)-2-but-2-yl)]-P-(2-carboxyethyl)-P-methyl phosphinate and an organic sulfate, preferably dodecyl sulphate and sulphonic acid, benzylamino benzene sulphonic acid, lignine sulphonic acid, 4-dimethylamino benzene diazosulphonate; a dithiocarbamic acid derivative and a phenol derivative, 2'-(2,4-dichlorophenoxy)-4'-chlorophenol, 2-(1-methyl-heptyl)-4,6-dinitrophenol, 2,4,5-trichlorophenol, 2-sec-butyl-4,6-dinitrophenol, 2-(1,1-dimethylethyl)-4,6-dinitrophenol.</p> |
