发明名称 PRODUCTION OF SOLID CATALYST COMPONENT FOR POLYMERIZING OLEFIN
摘要 PURPOSE: To obtain a solid catalyst component, suitable for the vapor polymerization of an olefin, good in shape, having a relatively large grain diameter and excellent in crush resistance in polymerization by using a melt mixture of an MG compound represented by specific compositional formula with an alcohol. CONSTITUTION: (A) A mixture of an Mg compound with an alcohol in a melted state is sprayed to provide (B) a solid component without evaporating the alcohol in the component (A). The alcohol is then partially removed from the component (B) to afford (C) a solid component. The components (A) and (B) are represented by formula I (R is a 1-10C alkyl; (m) is 3.0-6.0) and the component (C) is represented by formula II [(n) is 0.4-2.8] and has no peak produced at a diffraction angle 2θ=7-8 deg. and <=1/2 the maximum peak even when present in an X-ray diffraction spectrum in spraying the component (A), providing the component (B), partially removing the alcohol from the component (B), affording the component (C), bringing a titanium compound containing a halogen and an electron donor into contact with the component (C) by using an aliphatic hydrocarbon solvent having 90-180 deg.C boiling point at 110-135 deg.C, providing (D) a solid component, further bringing the resultant solid component into contact with the titanium compound and affording (E) a solid component which is the objective component.
申请公布号 JPH08127615(A) 申请公布日期 1996.05.21
申请号 JP19950222661 申请日期 1995.08.07
申请人 CHISSO CORP 发明人 UEI TOSHIHIRO;TACHIBANA MASAMI;SAITO JUN
分类号 C08F10/00;C08F4/60;C08F4/658;C08F110/00;C08F110/06;(IPC1-7):C08F4/658 主分类号 C08F10/00
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