A thermal transfer printing dyesheet comprising a sheet substrate having at least a thermal transfer dyecoat on one face and a heat resisting slipping layer on the other face, is characterised in that the heat resisting slipping layer comprises a silicone resin powder having silsesquioxane structure, and at least one of a metal salt powder of a higher fatty acid and a metal salt powder of a higher fatty acid phosphate. This dyesheet showed a superior travelling, has an outstanding freedom from scratching, does not develop creases and moreover its storage stability was an excellent one having no adverse effect on the dyecoat.
