Fluorinated polymers containing perfluoropolyoxyalkylene sequences and having thermoplastic elastomeric properties

摘要

Fluorinated polymers having thermoplastic elastomeric properties comprising in the macromolecule perfluoropolyoxyalkylene sequences of formula: -CF2O-(CF2CF2O)m-(CF2O)n-CF2-(I) where m/n=0.2+5, are obtained through polycondensation with suitable perfluoropolyoxyalkylene condensation monomers corresponding to formula (I), functionalized with suitable reactive groups and having a functionality at least equal to 1.97, preferably at least equal to 1.99. Such polymers are characterized by an average molecular weight at least 50%, preferably at least 100%, higher than that of the corresponding polymers obtained starting from perfluoropolyoxyalkylenes corresponding to formula (I) having a functionality not higher than 1.96.