发明名称 |
Process for the preparation of N,N'-substituted ureas |
摘要 |
A process for the preparation of substituted benzenes or benzenesulfonic acid and its derivatives comprising diazotisation of an aminobenzene or ortho-amino-benzenesulfonic acid derivative followed by homogeneous palladium-catalysed coupling with an olefine and heterogeneous palladium-catalysed hydrogenation of the olefinic substituent, wherein the homogeneous catalyst is reduced and precipitated as metal after the coupling in the reaction mixture and used as a heterogeneous palladium catalyst for the hydrogenation step. The process is particular suitable for the preparation N-benzenesulfon-N'-triazinyl-urea herbicides.
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申请公布号 |
US5508402(A) |
申请公布日期 |
1996.04.16 |
申请号 |
US19950451712 |
申请日期 |
1995.05.26 |
申请人 |
CIBA-GEIGY CORPORATION |
发明人 |
BAUMEISTER, PETER;SEIFERT, GOTTFRIED;STEINER, HEINZ |
分类号 |
C07B37/04;C07C303/22;C07C303/32;C07C309/39;C07D251/16;(IPC1-7):C07D251/46;C07D251/52;C07D239/69 |
主分类号 |
C07B37/04 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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