| 摘要 |
The microporous ceramic film is manufactured by (a) preparing a precursor by substituting beta diketone for alkoxide ligand of metallic alkoxide such as aluminum family alkoxide and transition metallic alkoxide, (b) hydrolysing the precursor with isopropanol, n-propanol or n-butanol as a solvent and nitric acid solution, (c) polymerizing it to obtain sol with below 3mm small particle size, (d) gelating this sol and sintering it at 150-600 deg.C. Beta diketone comprises one of alkyl acetoacetate having alkyl of C1-C6, 2,4-alkanediol and 3,5-alkanediol having alkyl of C1-C6, respectively.
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