摘要 |
Stereo-rigid metallocenes (I) contg. at least 2 opt. substd. cyclopentadienyl ligands, joined by a mono- or polycyclic ring system, in which at least one cyclopentadienyl gp. is annelated to this ring system, are new. Metallocenes with a 4-(eta5-3'-alkyl-cyclopentadienyl)-4,6,6-trimethyl- -(eta5-2-alkyl-4,5-tetrahydropentalene) ligand system are excluded. Also claimed are catalyst components contg. supported and/or prepolymerised (I); the prodn. of a cycloolefin copolymer (II) in the presence of a catalyst contg. cpd(s). (I) and cocatalyst(s) (III); (II) pe se; polymer alloys contg. (II); mouldings contg. (II) or the polymer alloy; and the use of (I) in the prodn. of (II).
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申请人 |
HOECHST AG, 65929 FRANKFURT, DE |
发明人 |
AULBACH, MICHAEL, DR., 65719 HOFHEIM, DE;BACHMANN, BERND, DR., 65817 EPPSTEIN, DE;KUEBER, FRANK, DR., 61440 OBERURSEL, DE;OSAN, FRANK, DR., 65779 KELKHEIM, DE;WELLER, THOMAS, DR., 55130 MAINZ, DE;HERRMANN, HANS-FRIEDRICH, DR., 64291 DARMSTADT, DE;ERKER, GERHARD, PROF. DR., 48159 MUENSTER, DE;PSIORZ, CHRISTIAN, DIPL.-CHEM., 48161 MUENSTER, DE |