发明名称 Stereo-rigid metallocenes useful in catalyst for cyclo-olefin copolymer prodn.
摘要 Stereo-rigid metallocenes (I) contg. at least 2 opt. substd. cyclopentadienyl ligands, joined by a mono- or polycyclic ring system, in which at least one cyclopentadienyl gp. is annelated to this ring system, are new. Metallocenes with a 4-(eta5-3'-alkyl-cyclopentadienyl)-4,6,6-trimethyl- -(eta5-2-alkyl-4,5-tetrahydropentalene) ligand system are excluded. Also claimed are catalyst components contg. supported and/or prepolymerised (I); the prodn. of a cycloolefin copolymer (II) in the presence of a catalyst contg. cpd(s). (I) and cocatalyst(s) (III); (II) pe se; polymer alloys contg. (II); mouldings contg. (II) or the polymer alloy; and the use of (I) in the prodn. of (II).
申请公布号 DE4432617(A1) 申请公布日期 1996.03.21
申请号 DE19944432617 申请日期 1994.09.14
申请人 HOECHST AG, 65929 FRANKFURT, DE 发明人 AULBACH, MICHAEL, DR., 65719 HOFHEIM, DE;BACHMANN, BERND, DR., 65817 EPPSTEIN, DE;KUEBER, FRANK, DR., 61440 OBERURSEL, DE;OSAN, FRANK, DR., 65779 KELKHEIM, DE;WELLER, THOMAS, DR., 55130 MAINZ, DE;HERRMANN, HANS-FRIEDRICH, DR., 64291 DARMSTADT, DE;ERKER, GERHARD, PROF. DR., 48159 MUENSTER, DE;PSIORZ, CHRISTIAN, DIPL.-CHEM., 48161 MUENSTER, DE
分类号 C07F17/00;C08F4/619;C08F4/6192;C08F4/659;C08F4/6592;C08F4/76;C08F10/00;C08F110/02;C08F110/06;C08F210/16;C08F210/18;(IPC1-7):C07F17/00;C07F7/00 主分类号 C07F17/00
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