发明名称 |
Process for the introduction of fluoro-carbon substituents in organic compounds |
摘要 |
A one pot process for the perfluoroalkylation and/or perfluoroacyloxylation of organic substrates is provided. The process comprises contacting a substrate with a perfluoroalkanoic anhydride in the presence of a an inorganic peroxygen compound at a temperature of greater than 10 DEG C. Substrates that can be perfluoroalkylated and/or perfluoroacyloxylated include alkylbenzenes, halogenated aromatic compounds, alkoxybenzenes, aryl benzenes, and aromatic and aliphatic disulphides. Preferably, the perfluoroalkanoic anhydride is trifluoroacetic anhydride and the inorganic peroxygen compound is sodium percarbonate. |
申请公布号 |
EP0700885(A1) |
申请公布日期 |
1996.03.13 |
申请号 |
EP19950113803 |
申请日期 |
1995.09.02 |
申请人 |
SOLVAY INTEROX LIMITED |
发明人 |
JONES, CRAIG WARREN;SANDERSON, WILLIAM RONALD;SANKEY, JOHN PHILLIP |
分类号 |
C07B37/04;C07C17/32;C07C41/30;C07C67/05;C07C319/14;C07C323/28 |
主分类号 |
C07B37/04 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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