发明名称 Optically active tolanes
摘要 A chiral dopant of the formula <IMAGE> I +TR <IMAGE> wherein ring A is 1,4-phenylene which is optionally substituted with one or more fluorine atoms, chlorine atoms, bromine atoms, cyano groups, or methyl groups, and in which one or two CH groups can be replaced by nitrogen, or is trans-1,4-cyclohexylene; Z is a single covalent bond, -CH2CH2-, -CH2O- or -OCH2-; X1,X2,X3,X4 each independently are hydrogen or fluorine; R1 is hydrogen, is alkyl with 1 to 12 carbon atoms which is optionally substituted with one or more fluorine or chlorine atoms and in which one or two non-adjacent CH2 groups can be replaced by -O-, is alkenyl with 2 to 12 carbon atoms, which is optionally substituted with one or more fluorine or chlorine atoms and in which one or two non-adjacent CH2 groups can be replaced by -O-, is a group of the formula <IMAGE> (a) and when R1 is bonded to an aromatic ring, can also be fluorine, chlorine, cyano, CF3, OCHF2 or -OCF3; R2,R3,R4,R5 are alkyl with 1 to 8 carbon atoms or alkenyl with 2 to 8 carbon atoms; n is 0 or 1; and * is a center of chirality.
申请公布号 US5498367(A) 申请公布日期 1996.03.12
申请号 US19950390609 申请日期 1995.02.17
申请人 HOFFMANN-LA ROCHE INC. 发明人 BUCHECKER, RICHARD;MARCK, GUY;SCHADT, MARTIN
分类号 G02F1/13;B01J23/44;C07B61/00;C07D317/32;C09K19/54;C09K19/58;(IPC1-7):C09K19/34;C09K19/30;C07D317/10 主分类号 G02F1/13
代理机构 代理人
主权项
地址